Titelseiten und Titelbilder


Nadeln des flexiblen Halbleiter-Materials SnIP; links im Bild nicht umgesetzer schwarzer Phosphor sowie Zinniodid (rot) - Foto: Andreas Battenberg / TUM
Video von Focus Online vom 26.06.2015
Kristalle aus halbleitendem schwarzem Arsen-Phosphor – Foto: Andreas Battenberg / TU München

Halbleitende Schichtmaterialien aus Phosphor und Arsen als Alternative zu Silizium

Pressemitteilung der TUM 09.07.2015


Veröffentlichungen nach Jahren


(118) A chemical, high-temperature way to Ag1.9Te via quasi-topotactic reaction of stuetzite-type Ag1.54Te – Structural and thermoelectrical properties
Franziska Baumer, Tom Nilges (2017), eingereicht.

(117) Towards MXPn-Type Compounds in the Systems Ge-I-Pn with Pn = P, As - New Insights in the Structures and Properties of Inverse Type I Clathrates 
Franziska Baumer, Felix Reiter and Tom Nilges
Z. Anorg. Allg. Chem. (2017).

(116) NaP7-xAsx, tuning of electronic properties in a polypnictide and heading towards helical one-dimensional semiconductors
Maximilian Baumgartner, Thomas Wylezich, Franziska Baumer, Markus Pielmeier, Anna Vogel, Richard Weihrich, Tom Nilges
Z. Anorg. Allg. Chem. (2017)

(115) Room-temperature high detectivity mid-infrared photodetectors based on black arsenic phosphorus
Mingsheng Long, Anyuan Gao, Peng Wang, Hui Xia, Claudia Ott, Chen Pan, Yajun Fu, Erfu Liu, Xiaoshuang Chen, Wei Lu, Tom Nilges, Jianbin Xu, Xiaomu Wang, Weida Hu, Feng Miao
Science Adv. (2017), 3, e1700589

(114) Co11Li[(OH)5O][(PO3OH)(PO4)5], a Lithium-Stabilized, Mixed-Valent Cobalt (II, III) Hydroxide Phosphate Framework
Jennifer Ludwig, Stephan Geprägs, Dennis Nordlund, Marca M. Doeff, Tom Nilges
Inorg. Chem. (2017).

(113) A yield-optimized access to double-helical SnIP via a Sn/SnI2 approach
A. Utrap, Ng Yan Xiang, Tom Nilges
J. Crystal Growth 475 (2017), 341-345.

(112) Phosphor, von rot bis Doppelhelix
André Utrap, Tom Nilges
Nachr. aus der Chemie (2017), 65, 430-433.

(111) Direct synthesis and characterization of mixed-valent Li0.5−δCoPO4, a Li-deficient derivative of the Cmcm polymorph of LiCoPO4 
Jennifer Ludwig, Carlos Alarcón-Suesca, Stephan Geprägs, Dennis Nordlund, Marca M. Doeff, Inés Puente Orench, and Tom Nilges
RSC Advances 7 (2017), 28069-28081

(110) Black Phosphorus Field-Effect Transistors with Work Function Tunable Contacts
Yuqiang Ma, Chenfei Shen, Anyi Zhang, Liang Chen, Yihang Liu, Jihan Chen, Qingzhou Liu, Zhen Li, Moh. R. Amer, Tom Nilges, Ahmad N. Abbas. Chongwu Zhou
ACS Nano (2017), 11 (7), 7126-7133.

(109) Inorganic SnIP-type double helices in main group chemistry
Maximilian Baumgartner, Richard Weihrich, Tom Nilges
Chem. Eur. J. 23 (2017), 6452-6457.

(108) Enhancement of Li ion conductivity by electrospun polymer fibers and direct fabrication of solvent-free separator membranes for Li ion batteries
Katharina M. Freitag, Holger Kirchhain, Leo van Wüllen, Tom Nilges
Inorg. Chem. 56 (4) (2017), 2100–2107.

(107) Particle size-controllable microwave-assisted solvothermal synthesis of the high-voltage cathode material LiCoPO4 using water/ethylene glycol solvent blends
Jennifer Ludwig, Dominik Haering, Marca M. Doeff, and Tom Nilges
Solid State Sci. 67 (2017), 100-109. 

(106) Breaking-News for Inorganic Clathrates
Franziska Baumer, Tom Nilges
Angew. Chem. 129 (13) (2017), 3474-3475.
Angew. Chem. Int. Ed. 56 (13) (2017), 3424-3425

(105) Synthesis, Characterization, and Device Application of Antimony-Substituted Violet Phosphorus – A Layered Material
Franziska Baumer, Yuqiang Ma, Chenfei Shen, Anyi Zhang, Liang Chen, Yihang Liu, Daniela Pfister, Tom Nilges, and Chongwu Zhou
ACS Nano 11(4) (2017), 4105-4113.

(104) Morphology-controlled microwave-assisted solvothermal synthesis of high-performance LiCoPO4 as a high-voltage cathode material for Li-ion batteries
Jennifer Ludwig, Cyril Marino, Dominik Haering, Christoph Stinner, Hubert A. Gasteiger, Tom Nilges
J. Power Sources 342 (2017), 214-223.

(103) Synthesis and characterization of metastable, 20 nm-sized Pna21-LiCoPO4 nanospheres
Jennifer Ludwig, Dennis Nordlund, Marca M. Doeff, Tom Nilges 
J. Solid State Chem. 248 (2017), 9-17. 



(102) In Situ Studies and Magnetic Properties of the Cmcm Polymorph of LiCoPO4 with a Hierarchical Dumbbell-Like Morphology Synthesized by Easy Single-Step Polyol Synthesis
Carlos Alarcón-Suesca, Jennifer Ludwig, Viktor Hlukhyy, Christoph Stinner, Tom Nilges
Inorganics 4 (2016), 35.

(101) Inorganic double helices in semiconducting SnIP
Daniela Pfister, Konrad Schäfer, Claudia Ott, Birgit Gerke, Rainer Pöttgen, Oliver Janka, Maximilian Baumgartner, Anastasia Efimova, Andrea Hohmann, Peer Schmidt, Sabarinathan Venkatachalam, Leo van Wüllen, Ulrich Schürmann, Lorenz Kienle, Viola Duppel, Eric Parzinger, Bastian Miller, Jonathan Becker, Alexander Holleitner, Richard Weihrich, Tom Nilges
Adv. Mater 28 (2016), 9783–9791.

(100) Fast track for silver (NV)
Tom Nilges
Nature 536 (2016), 150-151.

(99) Metal ion displacements in noncentrosymmetric chalcogenides La3Ga1.67S7, La3Ag0.6GaCh7 (Ch = S, Se), and La3MGaSe7 (M = Zn, Cd)
Abishek K Iyer, Wenlong Yin, Brent W Rudyk, Xinsong Lin, Tom Nilges, Arthur Mar
J. Solid State Chem. 243 (2016), 221-231.

(98) Facile, Ethylene Glycol-Promoted Microwave-Assisted Sol-vothermal Synthesis of High-Performance LiCoPO4 as a High-Voltage Cathode Material for Lithium-Ion Batteries
Jennifer Ludwig, Cyril Marino, Dominik Haering, Christoph Stinner, Dennis Nordlund, Marca M. Doeff, Hubert A. Gasteiger, Tom Nilges
RSC Advances 6 (2016), 82984 - 82994.

(97) Element allotropes and polyanion compounds of pnicogenes and chalcogenes: Stability, Mechanisms of Formation, controlled Synthesis, Characterization
Michael Schöneich, Andrea Hohmann, Peer Schmidt, Florian Pielnhofer, Frederik Bachhuber, Richard Weihrich, Oliver Osters, Marianne Köpf, Tom Nilges
Z. Krist. 232 (2016), 91-106.

(96) Polymorphism in Zintl-Phases ACd4Pn3: The modulated structures of NaCd4Pn3 with Pn = P, As
Carolin Grotz, Maximilian Baumgartner, Katharina M. Freitag, Franziska Baumer, Tom Nilges
Inorg. Chem. 55 (15)(2016), 7764-7776.

(95) Synthesis and structure determination of the first lead arsenide phosphide Pb2AsxP14−x (x ~ 3.7)
Konrad Schäfer, Korbinian Köhler, Franziska Baumer, Rainer Pöttgen, Tom Nilges
Z. Naturforsch B 71 (2016), 603-609.

(94) Synthesis and characterization of Cu(II)-halide 1-methylimidazolates
Michael Hörmannsdorfer, Ulrike Kahl and Tom Nilges
Z. Naturforsch. B 71 (2016), 105-112.



(93) Synthesis of bisisocyanate containing thiophenes and their use in PDMS based segmented polymers
Matthias Grübel, Simon Meister, Ulrich Schulze, Konstantinos N. Raftopoulus, Franziska Baumer Christine M. Papadakis, Tom Nilges, Bernhard Rieger,
Macro. Chem. Phys.  217 (1) (2015), 59-71.

(92) 1D-[P15] tubes in layered semiconducting AgP15
Carolin Grotz, Konrad Schäfer, Maximilian Baumgartner, Richard Weihrich, Tom Nilges
Inorg. Chem. 54 (2015), 10794-10800.

(91) Black Arsenic-Phosphorus: Layered Anisotropic Infrared Semiconductors with Highly Tunable Compositions and Properties
B. Liu, M. Köpf, A. A. Abbas, X. Wang, Q. Guo, Y. Jia, F. Xia, R. Weihrich, F. Bachhuber, F. Pielnhofer, H. Wang, R. Dhall, S. B. Cronin, M. Ge, X. Fang, T. Nilges, C. Zhou 
Adv. Mater. 27 (2015), 4423-4429.

(90) Nitrogen-Doping in ZnO via Combustion Synthesis?
Stefan Söllradl, Magnus Greiwe, Vanessa Bukas, Magnus Buchner, Marc Widenmeyer, Timur Kandemir, Tobias Zweifel, Anatoly Senyshyn, Sebastian Günther, Tom Nilges, Andreas Tuerler, Rainer Niewa
Chem. Mater. 27 (2015), 4188-4195.

(89) Black Phosphorus Gas Sensors
Ahmad N. Abbas, Bilu Liu, Liang Chen, Yuqiang Ma, Sen Cong, Noppadol Aroonyadet, Marianne Köpf, Tom Nilges, Chongwu Zhou
ACS Nano 9 (2015), 5618-5624.

(88) A rational approach to IrPTe – DFT and CalPhaD studies on phase stability, formation and structure of IrPTe 
Florian Pielnhofer, Michael Schöneich, Tobias Lorenz, Wenjie Yan, Tom Nilges, Richard Weihrich, Peer Schmidt
Z. Anorg. Allg. Chem. 641 (2015), 1099-1105.

(87) Van der Waals Interactions in Selected Allotropes of Phosphorus
F. Bachhuber, J. von Appen, R. Dronskowski, P. Schmidt, T. Nilges, A. Pfitzner, R. Weihrich
Z. Kristallogr. 230 (2015), 107-116.

(86) Synthesis, structure and properties of NaP7, a phosphorus rich polyphosphide
Carolin Grotz, Marianne Köpf, Maximilian Baumgartner, Laura Alice Jantke, Gabriele Raudaschl-Sieber, Thomas F. Fässler, Tom Nilges
Z. Anorg. Allg. Chem. 641 (2015), 1359-1399.

(85) Phosphorus rich d10 ion polyphosphides and selected materials
Melanie Bawohl, Tom Nilges
Z. Anorg. Allg. Chem. 641 (2015), 304-310.

(84) Low-activated Li-Ion Mobility and Metal to Semiconductor Transition in CdP2@Li Phases
Nadine Eckstein, Ilona Krüger, Frederik Bachhuber, Richard Weihrich, Jose E. Barquera-Lozada, Leo van Wüllen, Tom Nilges
J. Mater. Chem. A (2015), 3, 6484-649.

(83) Lithium Transition Metal Pnictides – Structural Chemistry, Electrochemistry and Function
Florian Winter, Rainer Pöttgen, Magnus Greiwe, Tom Nilges
Rev. Inorg. Chem. 35 (1) (2015), 1-25.





(82) Zr4CuSb7 – a PbFCl related Polyantimonide and Structure Relations of Zirconium Transition Metal Polyantimonides
 Magnus Greiwe, Tom Nilges
 Z. Naturforsch. B 69b (2014), 1124-1130.

(81) Anodic decomposition of trimethylboroxine as additive for high voltage Li-ion batteries
A. Freiberg, M. Metzger, D. Haering, S. Bretzke, S. Puravankara, T. Nilges, C. Stinner, C. Marino , H. A. Gasteiger
J. Electrochem. Soc. 161 (2014), A2255-A2261.

(80) Cu6Te3S – a Cu-filled Cr3Si-structure variant
Malte Giller, Carolin Grotz, Brent W. Rudyk, Arthur Mar, Tom Nilges
Z. Kristallogr. 229 (2014), 831-839.

(79) Die erweiterte Stabilitätsreihe der Phosphor-Allotrope
Frederik Bachhuber, Jörg von Appen, Richard Dronskowski, Peer Schmidt, Tom Nilges, Arno Pfitzner, Richard Weihrich
Angew. Chem. 53(43) (2014), 11629-11633.
Angew. Chem. Int. Ed. 126(43) (2014), 11813-11817.

(78) Access and in situ Growth of Phosphorene-Precursor Black Phosphorus
Marianne Köpf, Nadine Eckstein, Daniela Pfister, Carolin Grotz, Ilona Krüger, Magnus Greiwe, Thomas Hansen, Holger Kohlmann, Tom Nilges
J. Crystal Growth 405 (2014), 6-8.

(77) Structure and vibrational analyses of LiP15
Nadine Eckstein, Laura Alice Jantke, Thomas F. Fässler, János Mink, Markus Drees, Tom Nilges
Eur. J. Inorg. Chem. 30 (2014), 5135-5144.

(76) Lithium Transition Metal Pnictides – Structural Chemistry, Electrochemistry and Function
Florian Winter, Rainer Pöttgen, Magnus Greiwe, Tom Nilges
Rev. Inorg. Chem. 35 (1) (2015), 1-25.

(75) Polyantimonides as anode materials in battery applications
Magnus Greiwe, Tom Nilges
Progr. Solid State Chem. 42 (2014), 191-201.



(74) From Chalcogenides to Polychalcogenidehalides – First Identification in Mineral Samples
Ulrich Schürmann, Viola Duppel, Tom Nilges, Sergey Britvin, Vladimir A. Kovalenker,  Lorenz Kienle
Z. Anorg. Allg. Chem. 639 (2013), 2761-2766.

(73) Synthesis and Phase Relations of Single-Phase Fibrous Phosphorus
Nadine Eckstein, Andrea Hohmann, Tom Nilges, Peer Schmidt
Z. Anorg. Allg. Chem. 639 (2013), 2741-2743.

(72) Copper substitution and mixed cation effect in Ag10Te4Br3
Malte Giller, Melanie Bawohl, Alexandra P. Gerstle, Tom Nilges
Z. Anorg. Allg. Chem. 639 (2013), 2379-2381.

(71) Zirconium Transition Metal (Poly)antimonides – Syntheses, Characterization and Electrochemical Properties
Magnus Greiwe, Maximilian Krause, Oliver Osters, Alma Dorantes, Michele Piana, Tom Nilges
Z. Naturforsch. B 68b (2013), 979 – 986.

(70) Temperature initiated P-polymerization in solid [Cd3Cu]CuP10
Melanie Bawohl, Peer Schmidt, Tom Nilges
Inorg. Chem. 52 (20)(2013), 11895–11901. 

(69) Comments on Peierls-distorted Indium chains in In4Se3-x
Oliver Osters, Gustavo Blazek and Tom Nilges
Z. Anorg. Allg. Chem. 639 (2013), 497–501.

(68) Puzzling out the origin of the electrochemical activity of black P as negative electrode material with lithium for Lithium-ion batteries
Marian Cristian Stan, Jan von Zamory, Stefano Passerini, Tom Nilges, Martin Winter
J. Mater. Chem. A, 2013,1, 5293-5300.



(67) The layered Polyphosphide Ag3.73(4)Zn2.27(4)P16
Marianne Köpf, Oliver Osters, Melanie Bawohl, Tom Nilges 
Acta Cryst. E68 (2012), i91.

(66) The matryoshka effect (NV)
Tom Nilges
Nature, (2012), 489, 375-376.

(65) Synthese und Identifizierung metastabiler Verbindungen: Schwarzes Arsen - Fiktion oder Wirklichkeit? 
Oliver Osters, Tom Nilges, Frederik Bachhuber, Florian Pielnhofer, Richard Weihrich, Michael Schöneich, Peer Schmidt 
Angew. Chem. 124(12) (2012) 3049-3052.

(64) Cd4Cu7As, the first representative of a fully ordered, orthorhombically distorted MgCu2 Laves phase
Oliver Osters, Tom Nilges, Michael Schöneich, Peer Schmidt, Jan Rothballer, Florian Pielnhofer, Richard Weichrich
Inorg. Chem. 51 (2012) 8119–8127.

(63) Thermal analysis detecting equilibrium conditions: The use of the high temperature gas balance (HTGB) for thermogravimetric measurements 
Peer Schmidt, Michael Schöneich, Melanie Bawohl, Tom Nilges, Richard Weihrich 
J. Therm. Anal. Calorim. (2012) 110, 1511–1521



(62) Cu4.35Cd1.65As16: The first polyarsenic compound in the system Cu-Cd-As  
Oliver Osters, Tom Nilges 
Acta Cryst. E67 (2011), i62.

(61) The Influence of d10-d10 Interactions in Ag5Te1.8Se0.2Cl and Ag5Te1.6Se0.4Cl on Structural and Thermoelectric Properties 
Nadine Eckstein, Jean-Louis Bobet, Bernard Chevalier, Tom Nilges 
Z. Naturforsch. 66b(2011), 1005 – 1014.

(60) Ionenleitung im Festkörper - Ein wichtiger Aspekt in der Erschließung und Nutzung neuer Energiequellen(träger) -
Tom Nilges
Chemie & more, 1.11 (2011), 22-25.

(59) Trendberichte Festkörperchemie 2010
Wolfgang Bessler, Tom Nilges 
Nachrichten aus der Chemie, 59 (2011), 246-253.

(58) Effects of partial anion substitution on the thermoelectric properties of silver(I) chalcogenide halides in the system Ag5Q2X with Q = Te, Se and S and X = Br and Cl
Nadine Eckstein, Tom Nilges, Rodolphe Decourt, Jean-Louis Bobet, Bernard Chevalier
J. Solid State Chem. 184 (2011), 778-785.

(57) A Conceptional Approach to Materials for Resistivity Switching and Thermoelectrics
Oliver Osters, Melanie Bawohl, Jean-Louis Bobet, Bernard Chevalier, Rodolphe Decourt, Tom Nilges
Solid State Science 13 (2011), 944-947.



(56) Silver(I)(poly)chalcogenide Halides - Ion and Electron High Potentials
Tom Nilges,  Melanie Bawohl, Oliver Osters, Stefan Lange, Julia Messel
Z. Phys. Chem. 224 (2010), 1505-1531.

(55) New Arsenates (V) NaKAl2O[AsO4]2 and Na2KAl3[AsO4]4
Hamdi Ben Yahia, Tom Nilges, Ute Ch. Rodewald, Rainer Pöttgen 
Mater. Res. Bull. 45 (2010), 2017-2023.

(54) Reversible property switching, thermoelectric performance and d10-d10 interactions in Ag5Te2Cl 
Tom Nilges, Oliver Osters, Melanie Bawohl, Jean-Louis Bobet, Bernard Chevalier, Rodolphe Decourt, Richard Weihrich 
Chem. Mater. 22 (2010), 2946-2954.
(53) Structure Topology in Silver(I)-(poly)chalcogenide halides: A helpful Tool to understand Structure Relations and Properties 
Tom Nilges, Melanie Bawohl, Julia Messel, Oliver Osters 
Z. Anorg. Allg. Chem. 636 (2010), 15-18.
(52) Partial Anion Exchange in Ag23Te12X: The Solid Solutions Ag23Te12Cl1-xBrx, Ag23Te12Br1-yIy and Ag23Te12Cl1-zIz 
Oliver Osters, Tom Nilges
Z. Anorg. Allg. Chem. 636 (2010), 297-304.
(51) Highly dynamic chalcogen chains in silver(I) (poly)chalcogenide halides: A new concept for thermoelectrics?
Tom Nilges, Melanie Bawohl, Stefan Lange, Julia Messel, Oliver Osters
J. Electron. Mater. 39 (2010), 2096-2104.



(50) [Cd3Cu]CuP10, [Cd3Cu] Cluster Stabilized in an Adamantane-like Polyphosphide Substructure 
Melanie Bawohl, Tom Nilges
Z. Anorg. Allg. Chem. 635 (2009), 667-673.
(49) Reversible switching between p- and n-type conduction in the semiconductor Ag10Te4Br3 
Tom Nilges, Stefan Lange, Melanie Bawohl, Jens Markus Deckwart, H.-D. Wiemhöfer, Rodolphe Decourt, Bernard Chevalier, Julia Vannahme, Hellmut Eckert, Richard Weihrich
Nature Mater. 8 (2009), 101-108.
(48) The Unique Decomposition Behaviour of the Dimeric Dialkylaluminium Hydrazide [(Me3C)2Al-N(H)-N(H)-Me]2 - Butane versus Ammonia Elimination 
Werner Uhl, Thomas Abel, Tom Nilges, Friedhelm Rogel
Inorg. Chem. 48 (2009), 752-759.
(47) Pb5I2P28 , [PbP14]2- strands coordinated to a unique [Pb3I2]4+ unit 
Melanie Bawohl, Tom Nilges
Z. Anorg. Allg. Chem. 635 (2009), 307-311.
(46) Chemical bonding and Mößbauer spectroscopic investigations on ternary polyphosphides AgSbP14, [Ag3Sn]P7 and [Au3Sn]P7
Richard Weihrich, Stefan Lange, Tom Nilges
Solid State Sci. 11 (2009), 519-527



(45) Structure chemical aspects of Silver(I) chalcogenide halides and Preparation of the x = 1 member of the solid solution Ag5Te2 Cl1-xBrx 
Julia Messel, Tom Nilges
Z. Naturforsch. 63b (2008), 1077-1082.
(44) Electrochemical Properties of Ag5Te2 Cl0.8Br0.2, a Representative of the Solid Solution Ag5Te2 Cl1-xBrx 
Melanie Bawohl, Tom Nilges
Z. Naturforsch. 63b (2008), 1083-1086.
(43) New Phosphides La5Zn2P6 and Ce5Zn2P6 - the n = 4 members of the REZn2P2 x n(REP) Series 
Hannes Linke, Tom Nilges, Rainer Pöttgen
 Z. Anorg. Allg. Chem. 634 (2008), 2885-2888.
(42) Structural and 121Sb Mössbauer Spectroscopic Investigations of the Antimonide Oxides REMnSbO (RE = La, Ce, Pr, Nd, Sm, Gd, Tb) and REZnSbO (RE = La, Ce, Pr)
Inga Schellenberg, Tom Nilges, Rainer Pöttgen
 Z. Naturforsch. 63b (2008), 834-840.
(41) Mineralization routes to polyphosphides: Cu2P20 and Cu5InP16 
 Stefan Lange, Melanie Bawohl, Richard Weihrich, Tom Nilges
 Angew. Chem. 120 (2008), 5736-5739.
 Angew. Chem. Int. Ed. 47 (2008), 5654-5657.
(40) The solid solutions M19Q6X7 with M = Ag, Cu; Q = S, Se, Te and X = S, Se, Te
Tom Nilges, Julia Messel 
Z. Anorg. Allg. Chem. 634 (2008), 2185-2190.
(39) The silver(I) chalcogenide halides Ag19Te6Br7, Ag19Te6Br5.4I1.6 and Ag19Te5SeBr7
Tom Nilges, Julia Messel, Melanie Bawohl, Stefan Lange
Chem. Mater. 20 (2008), 4080-4091.
(38) Magnetical, Optical, and Electronic Properties of the Phosphide Oxides RE ZnPO (RE = Y, La-Nd, Sm, Gd, Dy Ho)
Hannes Lincke, Robert Glaum, Volker Dittrich, Marcus Tegel, Dirk Johrendt, Wilfried Hermes, Manfred H. Möller, Tom Nilges, Rainer Pöttgen
 Z. Anorg. Allg. Chem. 634 (2008), 1339-1348.
(37) Ternary Phosphides Ce3Zn2–xP4 and Ce4Zn2–xP5 – Stacking
Variants of CeP
6 Octahedra and ZnP4 Tetrahedra 
Hannes Lincke, Wilfried Hermes, Tom Nilges, Rainer Pöttgen
Solid State Sci. 10 (2008), 1480-1484.
(36) A fast low pressure transport route to large black phosphorus crystals 
Tom Nilges, Marcel Kersting, Thorben Pfeifer
J. Solid State Chem. 181 (2008), 1707-1711.

(35) Structures and thermal properties of silver(I) (poly)chalcogenide halide solid solutions Ag10Te4-(q,p)Q(q,p)Br3 
Tom Nilges, Melanie Bawohl
Z. Naturforsch. 63b (2008), 629-636.
(34) Crystal structures and thermal and electrical properties of the new silver (poly)chalcogenide halides Ag23Te12Cl and Ag23Te12Br 
Stefan Lange, Melanie Bawohl, Tom Nilges
Inorg. Chem. 47 (2008), 2625-2633.

(33) Crystal and electronic strucutre of La3Zn2-xP4 - New Phosphide with isolated P3- species 
Hannes Linke, Tom Nilges, Dirk Johrendt, Rainer Pöttgen
Solid State Sci. 10 (2008), 1006-1011.



Struktur-Eigenschafts-Beziehungen neuer Münzmetall-Chalkogenidhalogenide, Polyphosphide und verwandter Verbindungen 
Tom Nilges
Habilitationsschrift, Universität Münster (2007) low res. 2.6 MB
(high res. available from the author on demand) 

(32) Synthesis and Structure of Sr2Pd2In and Sr2Pt2In
Ihor Muts, Tom Nilges, Ute C. Rodewald, Vasyl' I. Zaremba, Rainer Pöttgen 
Z. Naturforsch. 62b (2007), 1563-1666

(31) Thiosilicate der Selten-Erd-Elemente: IV. Die quasi-isostrukturellen Verbindungen NaSm3S3[SiS4], CuCe3S3[SiS4], Ag0,63Ce3S2,63Cl0,37[SiS4] und Sm3S2Cl[SiS4] - Synthese, Kristallstruktur und Untersuchungen zur Silberionendynamik 
Ingo Hartenbach, Tom Nilges, Thomas Schleid
Z. Anorg. Allg. Chem. 633 (2007), 2445-2452.

(30) Ag10Te4Br3-xClx and Ag10Te4Br3-yIy: Structural and Electrical Property Tuning of a Mixed Conductor by Partial Anion Substitution 
Tom Nilges, Melanie Bawohl, Stefan Lange
Z. Naturforsch. 62b (2007), 955-964

(29) Au3SnP7@black phosphorus: An easy access to black phosphorus 
Stefan Lange, Peer Schmidt, Tom Nilges
Inorg. Chem. 46 (2007), 4028-4035

(28) Polymorphism, structural frustration and electrical properties of the mixed conductor Ag10Te4Br3 
Stefan Lange, Melanie Bawohl, Dirk Wilmer, Hinrich-Wilhelm Meyer, Hans-Dieter Wiemhöfer, Tom Nilges 
Chem. Mater. 19 (2007), 1401-1410



Struktur und optische Eigenschaften von LnZnPO (Ln = Y, La-Pr, Gd) 
Hannes Lincke, Rainer Pöttgen, Tom Nilges, Manfred H. Möller, Robert Glaum 
Z. Anorg. Allg. Chem. 632 (2006), 2110

M3SnCuP10 und M3SnP7 (M = Ag, Au): Neue [M3Sn] Heterocluster - Polyphosphide 
Tom Nilges, Stefan Lange 
Z. Anorg. Allg. Chem. 632 (2006), 2098

CuSnP14 und AgSbP14: Struktur-chemische Aspekte und Betrachtungen zur chemischen Bindung 
Tom Nilges, Stefan Lange 
Z. Anorg. Allg. Chem. 632 (2006), 2097.
Variation der Silber-Mobilität und Polymorphie in Silber(I)-polychalkogenid-halogeniden
Tom Nilges, Melanie Bawohl, Stefan Lange
Z. Anorg. Allg. Chem. 632 (2006), 2088.
(27) Ag3SnCuP10: [Ag3Sn] tetrahedra embedded between adamantane-type [P10] cages 
S. Lange, C. Peter Sebastian, L. Zhang, H. Eckert, T. Nilges 
Inorg. Chem. 45 (2006), 5878-5885

(26) Dimorphic CeZnPO and PrZnPO 
H. Lincke, T. Nilges, R. Pöttgen
Z. Anorg. Allg. Chem. 632 (2006), 1804-1808.
(25) 119Sn Mössbauer Spectroscopy and Chemical Bonding in AuTSn2 (T=Ni, Cu, Pd) 
S. Lange, F. M. Schappacher, D. Johrendt, T. Nilges, R.-D. Hoffmann, R. Pöttgen 
Z. Anorg. Allg. Chem. 632 (2006), 1432-1436.
(24) Au3SnCuP10 and Au3SnP7: Preparation and Crystal Structures of Au3Sn heterocluster polyphosphides. 
S. Lange, T. Nilges 
Z. Naturforsch. 61b (2006), 871-881.
(23) The Stannides AuNiSn2 and AuCuSn2: Bulk Synthesis and Superstructure Determination
S. Lange, T. Nilges, R.-D. Hoffmann, R. Pöttgen 
Z. Anorg. Allg. Chem. 632 (2006), 1163-1166.
(22) Li7B7Se15: A Novel Selenborate with a Zeolite-like Polymeric Anion Structure  
S. Pütz, M. Döch, A. Hammerschmidt, A. Lindemann, H. Eckert, T. Nilges, B. Krebs
Solid State Sci. 8 (2006), 764-772.
(21) Ag10Te4Br3: A new silver(I)(poly)chalcogenide halide solid electrolyte 
S. Lange, T. Nilges
Chem. Mater. 18 (2006), 2538-2544.
(20) La(OH)2IH2O: Closing a gap in rare earth hydroxide halide structure chemistry
T. Nilges
Z. Naturforsch. 61b (2006), 117-122.
(19) A new Preparative Approach to HgPbP14 Structure Type Materials: Crystal Structure of Cu0.73(1)Sn1.27(1)P14 and Characterisation of M1-xSn1+xP14 (M = Cu, Ag) and AgSbP14 
S. Lange, S. C. Peter, T. Nilges 
Z. Anorg. Allg. Chem. 632 (2006), 195-203

(18) Silver ion dynamics in the Ag5Te2Cl-Polymorphs Revealed by Solid State NMR Lineshape and Correlation Spectroscopies 
C. Brinkmann, S. Faske, M. Vogel, T. Nilges, A. Heuer, H. Eckert 
Phys. Chem. Chem. Phys., 8 (2006), 369-378



(17) Structures, phase transitions and electrical properties of Ag5Te2-ySeyCl (y = 0 - 0.7) 
T. Nilges, C. Dreher, A. Hezinger 
Solid State Sciences, 7 (2005), 79-88

(16) A structural differentiation of quaternary copper argyrodites: Structure - Property relations of high temperature ion conductors 
T. Nilges, A. Pfitzner
Z. Kristallogr., 220 (2005), 281-294.
(15) On the Solid Solutions Eu1-xPt2Inx, Gd1-xPt2Inx and Tm1-xNi2Inx 
M. Lukachuk, Y. M. Kalychak, T. Nilges, R. Pöttgen 
Z. Naturforsch. B, 60b (2005), 393-397

Crystal chemistry of silver (I) chalcogenide halides: Ag5Te2-ySyCl (y = 0-0.3) and related compounds 
T. Nilges. S. Lange 
Z. Kristallogr., Suppl. 22 (2005), 173. 

(14) Ag5Te2Cl1-xBrx (x = 0 - 0.65) and Ag5Te2-ySyCl (y = 0 - 0.3): Variation of Physical Properties in Silver(I) Chalcogenide Halides 
T. Nilges, S. Lange 
Z. Anorg. Allg. Chem. 631 (2005), 3002-3012



Ag5Te2-ySeyCl und Ag5Te2Cl1-xBrx: Struktur-Eigenschaftsvariationen durch Anionenaustausch 
T. Nilges, S. Lange 
Z. Anorg. Allg. Chem., 630/11 (2004), 1749.

(13) LixH12-x-y+z[P12OyN24-y]Xz (X = Cl, Br) - Oxonitridophosphate mit NPO-Zeolithstruktur 
S. Corell, N. Stock, O. Oeckler, J. Senker, T. Nilges, W. Schnick 
Z. Anorg. Allg. Chem., 630 (2004), 2205-2217.

(12) (CuBr)2P8Se3: Preparation, Structural and Vibrational Spectroscopic Characterisation of an Adduct of P8Se3 Cages to Cu2Br2 Rhombs 
S. Nilges, T. Nilges, H. Haeuseler, A. Pfitzner 
J. Mol. Struc., 706/1-3 (2004), 89-94.

(11) Structure-property relations and diffusion pathways of the silver ion conductor Ag5Te2Cl 
T. Nilges, S. Nilges, A. Pfitzner, Th. Doert, P. Böttcher 
Chem. Mater., 16 (2004), 806-812. DOI: 10.1021/cm031131c



(10) NMR Studies of Phosphorus Chalcogenide - Copper Iodide Coordination Compounds 
G. Brunklaus, J. C. C. Chan, H. Eckert, S. Reiser, T. Nilges, A. Pfitzner 
Phys. Chem. Chem. Phys., 5(23) (2003), 3768-3776. DOI:10.1039/b303610n.

(9) (CuBr)3P4Se4: A low symmetric variant of the (CuI)3P4Se4 structure type 
S. Reiser, T. Nilges und A. Pfitzner 
Z. Anorg. Allg. Chem., 629 (2003), 563-568.

(8) The Elusive Aldol Reaction of Enolates with Aldolates - A Highly Stereoselective Process Using Three Different Carbonyl Components 
M. Schmittel, A. Haeuseler, T. Nilges and A. Pfitzner 
Chem. Commun., 1 (2003), 34-35. DOI: 10.1039/b209536j. 



(8) Preparation, Structural, Raman and Impedance Spectroscopic Characterisation of the silver ion conductor (AgI)2Ag3SbS3 
T. Nilges, S. Reiser, J. H. Hong, E. Gaudin, and A. Pfitzner 
Phys. Chem. Chem. Phys., 4(23) (2002), 5888-5894. DOI:10.1039/b203556a.

(7) CuClSe1.53Te0.47 and CuClSe0.56Te1.44: Structural and Vibrational Spectroscopic Investigations on Copper(I) Chalcogen Chlorides 
T. Nilges, S. Zimmerer, D. Kurowski, A. Pfitzner
Z. Anorg. Allg. Chem., 628 (2002), 2809-2814.

Strukturchemische und spektroskopische Untersuchungen an CuClSe2-xTex Phasen 
T. Nilges, S. Zimmerer, A. Pfitzner
Z. Anorg. Allg. Chem., 628 (2002), 2203



(6) Zincation of primary amines: synthesis and structures of dimeric alkylzinc amides
M. Westerhausen, T. Bollwein, A. Pfitzner, T. Nilges, H.-J. Deiseroth 
Inorg. Chim. Acta, 312 (2001), 239-244. 



(5) Crystal Structure of cesium-o-selenosilicate, Cs4SiSe4 
J. Schlirf, H.J. Deiseroth, T. Nilges 
Z. Kristallogr. - New Cryst. Struct., 215(3) (2000), 343-344.

(4) (CuI)2P8Se3: An Adduct of D3 symmetrical P8Se3 Cage Molecules with Cu2I2 Rhombs 
A. Pfitzner, S. Reiser, T. Nilges 
Angew. Chem., Int. Ed., 39 (2000), 4160-4162.

(4) (CuI)2P8Se3: Ein Addukt von D3-symmetrischen P8Se3-Käfigmolekülen an Cu2I2-Rhomben 
A. Pfitzner, S. Reiser, T. Nilges 
Angew. Chem., 112 (2000), 4328-4330.

(3) Synthese und Struktur von Sr6P8-Polyedern in gemischten Phosphaniden/Phosphandiiden des Strontiums 
M. Westerhausen, Ch. Birg, M. Krofta, P. Mayer, T. Seifert, H. Nöth, A. Pfitzner, T. Nilges, H.-J. Deiseroth 
Z. Anorg. Allg. Chem., 626 (2000), 1073-1080.

(AgI)2Ag3SbS3: Ein neuer Silberionenleiter. 
T. Nilges, A. Pfitzner 
Z. Kristallogr. Suppl. 17 (2000), 147. 



(2) Composite copper chalcogenide halides: neutron powder diffraction of CuClCu2TeS3 and electrical properties of CuClCu2TeS3, (CuI)2Cu3SbS3, and (CuI)3Cu2TeS3 
A. Pfitzner, S. Reiser, T. Nilges, W. Kockelmann 
J. Solid State Chem., 147 (1999), 170-176.

(1) CuBrSe2: A Metastable Compound in the System CuBr/Se. 
A. Pfitzner, T. Nilges, H.-J. Deiseroth 
Z. Anorg. Allg. Chem., 625 (1999), 201-206.

Untersuchungen im System CuBrSe3 und CuBrS3
T. Nilges, A. Pfitzner 
Z. Kristallogr. Suppl. 16 (1999), 51. 






Technische Universität München
17.07.2015 / EP15176311.7
WO 2017/008979 A1